, 2008 and Souza and Oliveira, 2009). Thus the slot-rectangular spouted bed with inlet air drying temperature 90 °C was more appropriate for obtaining higher values of product recovery and lower accumulated mass values. The main characteristics in relation to chitosan powder quality are deacetylation degree and molecular weight (Rinaudo, 2006). Other fundamental quality aspects are particle size (Piccin, Vieira, Gonçalves,

Dotto, & Pinto, 2009) and color (Srinivasa et al., 2004). These characteristics determine Epacadostat manufacturer the chitosan application range (Rinaudo, 2006), and can be influenced by drying conditions (Batista et al., 2007, Srinivasa et al., 2004 and Youn et al., 2009), so, it is important to determine the best drying condition in the spouted bed in order to obtain commercial moisture content, without modifying the product quality. Table 2 shows influence of temperature and geometry in chitosan powder quality. In Table 2 it can be observed that in all drying experiments, PD0332991 chemical structure chitosan deacetylation degree was equal to the initial value, so, temperature and geometry

did not affect deacetylation degree (p > 0.05). Similar behavior was obtained by Youn et al. (2009) in chitosan sun drying at different times. In this case deacetylation degree was not affected, having a range of 81.91 ± 0.73 to 82.73 ± 0.40%. The spouted bed geometry did not affect chitosan final moisture content (p > 0.05), however, a temperature increase caused a decrease in chitosan final moisture content ( Table 2). When temperature is increased, convection heat transfer is facilitated, so, evaporation water rate is increased. In addition, effective diffusivity is increased, increasing water mass transfer rate within the material. Similar behavior was obtained by Wachiraphansakul and Devahastin (2007) in drying MYO10 of okara in a spouted bed. Passos et al. (2008) found moisture content powder between 3 g 100 g−1 and 16 g 100 g−1 (w.b.) in drying of black liquor in a spouted bed; in this case, inlet temperatures were 80 °C, 100 °C and 120 °C, showing that powder moisture content depend on inlet air temperature. Although moisture content is dependent of

temperature, commercial moisture content (until 10 g 100 g−1 w.b.) was obtained in all experiments. The temperature increase caused an increase in powder particle size (p ≤ 0.05), and more fine powder was obtained in slot-rectangular geometry ( Table 2). This behavior can be explained because in slot-rectangular spouted bed, the air drying velocity was higher and attrition effect was more pronounced, thus finer powder was found. In relation to temperature effect, due to the modifications in material proprieties with temperature increase, bigger particle sizes were obtained at higher temperature. Similar behavior was obtained by Shuhama et al. (2003), in experimental production of annatto powder in a spouted bed. In this case the temperature increase from 80 °C to 100 °C caused an increase in particle size from 21.6 to 65.5 μm.